689 research outputs found
Effect of hydrophobic solutes on the liquid-liquid critical point
Jagla ramp particles, interacting through a ramp potential with two
characteristic length scales, are known to show in their bulk phase
thermodynamic and dynamic anomalies, similar to what is found in water. Jagla
particles also exhibit a line of phase transitions separating a low density
liquid phase and a high density liquid phase, terminating in a liquid-liquid
critical point in a region of the phase diagram that can be studied by
simulations. Employing molecular dynamics computer simulations, we study the
thermodynamics and the dynamics of solutions of hard spheres (HS) in a solvent
formed by Jagla ramp particles. We consider the cases of HS mole fraction x =
0.10, 0.15 and 0.20, and also the case x = 0.50 (a 1:1 mixture of HS and Jagla
particles). We find a liquid-liquid critical point, up to the highest HS mole
fraction; its position shifts to higher pressures and lower temperatures upon
increasing x. We also find that the diffusion coefficient anomalies appear to
be preserved for all the mole fractions studied.Comment: 8 pages, 7 figures, 1 table. In press (Phys. Rev. E
Multifractal Properties of the Random Resistor Network
We study the multifractal spectrum of the current in the two-dimensional
random resistor network at the percolation threshold. We consider two ways of
applying the voltage difference: (i) two parallel bars, and (ii) two points.
Our numerical results suggest that in the infinite system limit, the
probability distribution behaves for small current i as P(i) ~ 1/i. As a
consequence, the moments of i of order q less than q_c=0 do not exist and all
current of value below the most probable one have the fractal dimension of the
backbone. The backbone can thus be described in terms of only (i) blobs of
fractal dimension d_B and (ii) high current carrying bonds of fractal dimension
going from to d_B.Comment: 4 pages, 6 figures; 1 reference added; to appear in Phys. Rev. E
(Rapid Comm
Aging in short-ranged attractive colloids: A numerical study
We study the aging dynamics in a model for dense simple liquids, in which
particles interact through a hard-core repulsion complemented by a short-ranged
attractive potential, of the kind found in colloidal suspensions. In this
system, at large packing fractions, kinetically arrested disordered states can
be created both on cooling (attractive glass) and on heating (repulsive glass).
The possibility of having two distinct glasses, at the same packing fraction,
with two different dynamics offers the unique possibility of comparing --
within the same model -- the differences in aging dynamics. We find that, while
the aging dynamics of the repulsive glass is similar to the one observed in
atomic and molecular systems, the aging dynamics of the attractive glass shows
novel unexpected features.Comment: 8 pages, 11 figures, submited to Journal of Chemical Physic
Dynamics of Surface Roughening with Quenched Disorder
We study the dynamical exponent for the directed percolation depinning
(DPD) class of models for surface roughening in the presence of quenched
disorder. We argue that for dimensions is equal to the exponent
characterizing the shortest path between two sites in an
isotropic percolation cluster in dimensions. To test the argument, we
perform simulations and calculate for DPD, and for
percolation, from to .Comment: RevTex manuscript 3 pages + 6 figures (obtained upon request via
email [email protected]
Phase diagram of a two-dimensional system with anomalous liquid properties
Using Monte Carlo simulation techniques, we calculate the phase diagram for a
square shoulder-square well potential in two dimensions that has been
previously shown to exhibit liquid anomalies consistent with a metastable
liquid-liquid critical point. We consider the liquid, gas and five crystal
phases, and find that all the melting lines are first order, despite a small
range of metastability. One melting line exhibits a temperature maximum, as
well as a pressure maximum that implies inverse melting over a small range in
pressure.Comment: 11 pages, 13 figure
Statistical Properties of Business Firms Structure and Growth
We analyze a database comprising quarterly sales of 55624 pharmaceutical
products commercialized by 3939 pharmaceutical firms in the period 1992--2001.
We study the probability density function (PDF) of growth in firms and product
sales and find that the width of the PDF of growth decays with the sales as a
power law with exponent . We also find that the average
sales of products scales with the firm sales as a power law with exponent
. And that the average number products of a firm scales
with the firm sales as a power law with exponent . We
compare these findings with the predictions of models proposed till date on
growth of business firms
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